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@@ -41,4 +41,15 @@ Program:
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- 判断同一个碳原子上面的氢,是否是非对映质子
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- 判断同一个碳原子上面的氢,是否是非对映质子
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+回答标题:首先通过对称性判断化学等价性,然后考察是否磁等价;这之外需要考察快速交换导致的化学等价性质。
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+**if a plane of symmetry or an axis of symmetry makes two or more nuclei equivalent by symmetry, then they are said to be chemically equivalent.** 这个出 Rotational axis or Symmetry plane (or by a rapid exchange mechanism)
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+困难在判断磁等价,以及快速交换的化学等价。
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+![](https://1.bp.blogspot.com/-H-hOyemf4HY/X3Mqgm_3LSI/AAAAAAAALoI/fvKVUli0j3EB8gMteSLeopVNBaTsnD1XACLcBGAsYHQ/w640-h360/pic%2B4.tif)
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+![](https://1.bp.blogspot.com/-jl-v1bt-9KM/X3MqpZUT_xI/AAAAAAAALoM/kYv6JR7BEdU8EODIteHupzK9eNc_bpLzACLcBGAsYHQ/w640-h264/Pic%2B8.jpg)
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+![](https://1.bp.blogspot.com/-Sj9ofM95cGQ/X3iRQP_3n5I/AAAAAAAALp8/L3dJvHpc1iYRyXYdAynBILxsQuTckogewCLcBGAsYHQ/w640-h360/pic%2B7.jpg)
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+![](https://1.bp.blogspot.com/-Oy8CsSp74EA/X3iRoN6aURI/AAAAAAAALqE/pPIPSDJjtm8Zo2swcTd1KiiJjZ0nB-q3gCLcBGAsYHQ/w640-h176/Pic%2B14.tif)
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